The 4.0 is a pretty reliable motor... crank sensor would be the big thing I would be wary of. If you feel you need to, swap it out and carry your old one as a spare. TPS can be finicky sometimes too, but you can still limp home with a non-functional TPS... if you wanted to, carry a spare for that one. Maybe a spare coil if you wish, I've never had one die on me though. Honestly, I've never had problems with any of the other electronics on any of my various 4.0 rigs I've had over the years, and that says something as far as problem areas. CPS is really the major one... and sometimes it's not the CPS itself but the connector to the CPS gets corroded and doesn't make a good connection, and simply unplugging and re-plugging or wiggling it will help.
As far as other good things to carry goes... In addition to what Gary said, I would also carry a spare serpentine belt and idler pulley, a spare upper and lower rad hose, some hose clamps and a length of heater hose. Cooling system failures will leave you dead in the water (no pun intended)... been there, done that... don't want to do it again, so I carry spares and enough water to refill the coolant if I should need to.